Jeez, I didn't even notice in your picture that the bolt wasn't into the head. My powers of observation fail me.
Looking at a picture of my engine before the alternator was installed, it looks like the bolt holes are in the same place between the Ed L. Brock heads and the W2s. My brackets are reproductions as well, and they fit perfectly. At first I thought they were defective, but I was trying to install the bracket in the wrong place on the alternator (it was a fore/aft issue). I was sent another set, and by the time they arrived I'd figured out my mistake. I bought them from Van's Auto, and they came in a Ziploc bag with an instruction sheet--which I obviously ignored--brackets, spacers, and bolt.
Something's horseshit here, especially if you have a bracket that
does fit. You clearly have a '70-up timing cover since the marks are on the driver's side, an aluminum pump which is also 1970 & newer, and repro brackets for the same application. The holes in the heads never changed position across LA production to my knowledge. If the bracket that fits has one curved side and a hole through the middle of it, that's a 1969-older part for use with an iron water pump. That setup used different spacers, including one behind the bracket at the timing cover, due to the cast-iron water pump. Since the holes in the head never changed, it makes no sense why one bracket fits and the other doesn't.
As an additional snafu, the early bracket is flat and mounts the alternator in a different position laterally. The '70-up pulleys won't align to the alternator pulley using the '69-older bracketry. Literally everything changed with the aluminum water pump, so there's no mixing and matching across the dividing line without some kind of fabrication or butchery.
I'm not sure what the solution is, because I really can't figure out why it won't align.
As far as the pulleys go, the 318 numbers I posted from the 1974 parts book are common on eBay, which isn't surprsing since both are probably the most-common Mopar pulleys on the planet. One user posted photos with depth measurements of both his
crank and
water pump pulleys, showing they'll align. Both are "best offer" listings. Regarding new, if Bouchillon's information is to be believed (and I see no reason to doubt them), then 440Source sells
the same crankshaft pulley for $50 less. 440Source's pulley measurements also align with those in the eBay listing. I've never dealt with 440Source but I've heard wonderful things. I
have dealt with Bouchillon and will avoid doing so at any cost in the future. I'm not alone.
It does look like dude's stroker motor would align with the bolt-on timing "mark" you have. However, with a Chinese crank and just-as-Asian damper, all bets are off. With a factory steel crank, OE damper and timing cover, my W2 engine's timing marks are as dead-nuts at TDC as one could hope. They're misaligned by maybe 1/2°, which I'd call "close enough for what I'm doing". That's not to say yours is, of course, so making a piston stop out of an old spark plug is a great idea.